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Beilstein J. Org. Chem. 2009, 5, No. 83, doi:10.3762/bjoc.5.83
Graphical Abstract
Figure 1: The molecular structures of 1,12-dicarba-closo-dodecaborane (12-vertex p-carborane, A) and 1,10-dic...
Figure 2: The molecular structures of derivatives 1–20.
Scheme 1: Preparation of diesters 16[n].
Scheme 2: Preparation of esters 18–20.
Scheme 3: Preparation of phenol 24.
Figure 3: Partial DSC trace for 16D[6]. Heating rate 5 K/min.
Figure 4: Optical textures of 16D[6] obtained for the same region of the sample upon cooling: (a) SmA growing...
Figure 5: The change in the clearing temperature ΔTc upon substitution –OCH2– → –CH2CH2– in selected pairs of...
Figure 6: The change in the clearing temperature ΔTc upon replacing of the –OCH2– connecting group with anoth...
Figure 7: Equilibrium ground state geometries (B3LYP/6-31G(d)) for benzene derivatives: ethoxybenzene (25), p...